Hi nickj and welcome to the Vodafone eForum.
In short, the dongle and OS are compatible, especially if you are using the latest version of VMC.
I've two or three questions that will assist in diagnosing your issue:
Are there any lights flashing on the modem? If so, what sort of colour/frequency?
Also, does Windows make a noise to say it has recognised you plugging the modem in?
Also, do you see a Vodafone logo under "devices with removable storage" in My Computer?
The USB modem has to attach itself as a CD Drive in order to load the software and initialise the modem. The problem is, it can sometimes be a bit picky about which drive letter it attaches itself to, and if the one it wants (usually either E or F) is already taken, you see the icon in My Computer appear and then disappear on its own.
If one of your new partitions takes one of the lower letters (D, E, F, G, for example), can you try moving them to higher drive letters out of the way, using the Disk Management tool?
Let me know how this affects the issue.
Regards
Trev
eForum Team