Hi,
Unfortunately a Samsung Galaxy s6 or Samsung Galaxy s6 Edge hsve to purchased directly from Vodafone to be eligible for Wifi Calling.
"To take advantage of Wi-Fi Calling, you need:
A Pay monthly Red or Red Value Bundle, Red+ or Business Premier*
A compatible device:
iPhone 6s or 6s Plus
A Samsung Galaxy S6 or S6 edge bought directly from Vodafone at one of our stores, online or by phone through our customer service team"
from http://www.vodafone.co.uk/explore/network/network-improvements/wi-fi-calling/index.htm
Current Phone >
Samsung Galaxy s²⁴ Ultra 512gb.
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